Muñiz
Research group
Abstract
The Muñiz group devotes efforts to develop sustainable synthetic methodology for advanced oxidative transformation of organic molecules. For 2016, work in this area has provided new transformations that are based on molecular iodine reagents and catalysts and which include pioneering examples of enantioselective alkene oxidations under intermolecular reaction control.
Topics addressed
- Iodine(I/III)-Catalysed dioxygenation of styrenes
- Iodine-mediated C-H amination
- Palladium catalysed amination reactions.
Articles
“Structurally Defined Molecular Hypervalent Iodine Catalysts for Intermolecular Enantioselective Reactions“
Angew. Chem. 2016, 128, 422; Angew. Chem. Int. Ed. 2016, 55, 413
S. Haubenreisser, T. H. Wöste, C. Martínez, K. Ishihara, K. Muñiz
“Enantioselective Vicinal Diacetoxylation of Alkenes under Chiral Iodine(III) Catalysis“
Synthesis 2016, 48, 816
T. H. Wöste, K. Muñiz
“Substitution Effects of Hypervalent Iodine(III) Reagents in the Diamination of Styrene “
J. Org. Chem. 2016, 81, 6118
R. M. Romero, J. A. Souto, K. Muñiz
“DFT Rationalization of the Diverse Outcomes of the Iodine(III)-Mediated Oxidative Amination of Alkenes “
Chem. Eur. J. 2016, 22, 7545
I. Funes-Ardoiz, W. M. C. Sameera, R. M. Romero, C. Martínez, J. A. Souto, K. Muñiz, F. Maseras
“Sterically Congested 2,6-Disubstituted Anilines from Direct C-N Bond Formation at Iodine(III)“
Angew. Chem. 2016, 128, 13529; Angew. Chem. Int. Ed. 2016, 55, 13335
N. Lucchetti, M. Scalone, S. Fantasia, K. Muñiz
“An Improved Catalyst for Iodine(I/III)-Catalysed Intermolecular C-H Amination“
Adv. Synth. Catal. 2016, 358, 2093
N. Lucchetti, M. Scalone, S. Fantasia, K. Muñiz
“Indole Synthesis through Sequential Electrophilic N-H and C-H Bond Activation using Iodine(III) Reactivity“
Chem. Eur. J. 2016, 22, 4351
L. Fra, K. Muñiz
“Iodine(III)-Mediated Selective Intermolecular C-H Amination for the Chemical Diversification of Tryptamines“
J. Org. Chem. 2016, 81, 6496
A. Bosnidou, A. Millán, J. Cevallos, C. Martínez, K. Muñiz
“N-Iodosuccinimide promoted Hofmann-Löffler Reactions of Sulfonamides under Visible Light “
Org. Lett. 2016, 18, 436
C. Q. O’Broin, P. Fernández, C. Martínez, K. Muñiz
“Towards Uniform Iodine-Catalysis: Intramolecular C-H-Amination of Arenes under Visible Light“
Chem. Eur. J. 2016, 22, 9929
C. Martínez, A. Bosnidou, S. Allmendinger, K. Muñiz
“Defined Palladium Phthalimidato Catalysts for Improved Oxidative Amination“
Chem. Eur. J. 2016, 22, 7367
C. Martínez, K. Muñiz
“Regioselective Intermolecular Diamination and Aminooxygenation of Alkenes with Saccharin“
Org. Lett. 2016, 18, 2998
C. Martínez, E. Pérez, Á. Iglesias, E. C. Escudero-Adán, K. Muñiz
“The Quest for Palladium-Catalysed Alkyl-Nitrogen Bond Formation“
Chem. Rec. 2016, 16, 2561
C. Martínez, Á. Iglesias, K. Muñiz
“Formación de Enlaces Alquilo-Nitrógeno Catalizada por Paladio“
Anales de Química 2016, 112, 142
C. Martínez, K. Muñiz